Splitting CO2 into CO and O2 by a single catalyst.

Abstract:

:The metal complex [(tpy)(Mebim-py)Ru(II)(S)](2+) (tpy = 2,2' : 6',2''-terpyridine; Mebim-py = 3-methyl-1-pyridylbenzimidazol-2-ylidene; S = solvent) is a robust, reactive electrocatalyst toward both water oxidation to oxygen and carbon dioxide reduction to carbon monoxide. Here we describe its use as a single electrocatalyst for CO(2) splitting, CO(2) → CO + 1/2 O(2), in a two-compartment electrochemical cell.

authors

Chen Z,Concepcion JJ,Brennaman MK,Kang P,Norris MR,Hoertz PG,Meyer TJ

doi

10.1073/pnas.1203122109

subject

Has Abstract

pub_date

2012-09-25 00:00:00

pages

15606-11

issue

39

eissn

0027-8424

issn

1091-6490

pii

1203122109

journal_volume

109

pub_type

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