当前位置： SCI文献检索 > INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES期刊下所有文献 > Spectroscopic study of solvent effects on the electronic absorption spectra of flavone and 7-hydroxyflavone in neat and binary solvent mixtures.

Spectroscopic study of solvent effects on the electronic absorption spectra of flavone and 7-hydroxyflavone in neat and binary solvent mixtures.

Abstract：

:The solvatochromic characteristics of flavone and 7-hydroxyflavone were investigated in neat and binary solvent mixtures. The spectral shifts of these solutes were correlated with the Kamlet and Taft parameters (α, β and π*) using linear solvation energy relationships. The multiparametric analysis indicates that both specific hydrogen bond donor ability and non-specific dipolar interactions of the solvents play an important role in absorption maxima of flavone in pure solvents. The hydrogen bond acceptor ability of the solvent was the main parameter affecting the absorption maxima of 7-hydroxyflavone. The simulated absorption spectra using a TD-DFT method were in good agreement with the experimental ones for both flavones. Index of preferential solvation was calculated as a function of solvent composition. Preferential solvation by ethanol was detected in cyclohexane-ethanol and acetonitrile-ethanol mixtures for flavone and in acetonitrile-ethanol mixtures for 7-hydroxyflavone. These results indicate that intermolecular hydrogen bonds between solute and solvent are responsible for the non-linear variation of the solvatochromic shifts on the mole fraction of ethanol in the analyzed binary mixtures.

journal_name

Int J Mol Sci

journal_title

International journal of molecular sciences

authors

Sancho MI,Almandoz MC,Blanco SE,Castro EA

doi

10.3390/ijms12128895

subject

Has Abstract

pub_date

2011-01-01 00:00:00

pages

8895-912

issue

12

issn

1422-0067

pii

ijms-12-08895

journal_volume

12

pub_type

杂志文章

相关文献

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES文献大全
  • Expression Patterns of Genes Involved in Ascorbate-Glutathione Cycle in Aphid-Infested Maize (Zea mays L.) Seedlings.

    abstract：:Reduced forms of ascorbate (AsA) and glutathione (GSH) are among the most important non-enzymatic foliar antioxidants in maize (Zea mays L.). The survey was aimed to evaluate impact of bird cherry-oat aphid (Rhopalosiphum padi L.) or grain aphid (Sitobion avenae F.) herbivory on expression of genes related to ascorbat...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms17030268

    authors： Sytykiewicz H

    更新日期：2016-02-23 00:00:00

  • Interleukin-1 receptor antagonist reduces neonatal lipopolysaccharide-induced long-lasting neurobehavioral deficits and dopaminergic neuronal injury in adult rats.

    abstract：:Our previous study showed that a single lipopolysaccharide (LPS) treatment to neonatal rats could induce a long-lasting neuroinflammatory response and dopaminergic system injury late in life. This is evidenced by a sustained activation of microglia and elevated interleukin-1β (IL-1β) levels, as well as reduced tyrosin...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms16048635

    authors： Pang Y,Tien LT,Zhu H,Shen J,Wright CF,Jones TK,Mamoon SA,Bhatt AJ,Cai Z,Fan LW

    更新日期：2015-04-17 00:00:00

  • Transcriptome Profiling Reveals Transcriptional Regulation by DNA Methyltransferase Inhibitor 5-Aza-2'-Deoxycytidine Enhancing Red Pigmentation in Bagged "Granny Smith" Apples (Malus domestica).

    abstract：:The red color of apples (Malus domestica) is an attractive trait for consumers. The green skinned "Granny Smith" cultivar develops red pigmentation after bagging treatment. DNA methylation plays an important role in various developmental processes in plants. To explore the possible functions of DNA methylation in the ...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms19103133

    authors： Ma C,Liang B,Chang B,Liu L,Yan J,Yang Y,Zhao Z

    更新日期：2018-10-12 00:00:00

  • Metabolomic Approach in STEMI-Patients Undergoing Left Ventricular Remodeling.

    abstract：:Left ventricular remodeling (LVR) occurring after ST-segment elevation myocardial infarction (STEMI) is frequent and severe. We present a metabolomic approach as an attempt to reveal unknown biomarkers associated with post-STEMI LVR. Out of 192 consecutive patients with successfully revascularized STEMI, 32 presented ...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20020289

    authors： Garcia G,Chao de la Barca JM,Mirebeau-Prunier D,Reynier P,Furber A,Prunier F,Bière L

    更新日期：2019-01-12 00:00:00

  • SPACIA1/SAAL1 Deletion Results in a Moderate Delay in Collagen-Induced Arthritis Activity, along with mRNA Decay of Cyclin-dependent Kinase 6 Gene.

    abstract：:This study was performed to elucidate the molecular function of the synoviocyte proliferation-associated in collagen-induced arthritis (CIA) 1/serum amyloid A-like 1 (SPACIA1/SAAL1) in mice CIA, an animal model of rheumatoid arthritis (RA), and human RA-synovial fibroblasts (RASFs). SPACIA1/SAAL1-deficient mice were g...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms19123828

    authors： Fujii R,Komatsu R,Sato T,Seki I,Konomi K,Aono H,Niki H,Yudoh K,Nishioka K,Nakajima T

    更新日期：2018-11-30 00:00:00

  • Combined Metabolome and Transcriptome Analyses Reveal the Effects of Mycorrhizal Fungus Ceratobasidium sp. AR2 on the Flavonoid Accumulation in Anoectochilus roxburghii during Different Growth Stages.

    abstract：:Anoectochilus roxburghii is a traditional Chinese herb with high medicinal value, with main bioactive constituents which are flavonoids. It commonly associates with mycorrhizal fungi for its growth and development. Moreover, mycorrhizal fungi can induce changes in the internal metabolism of host plants. However, its r...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms21020564

    authors： Zhang Y,Li Y,Chen X,Meng Z,Guo S

    更新日期：2020-01-15 00:00:00

  • The Role of Cell-Penetrating Peptide and Transferrin on Enhanced Delivery of Drug to Brain.

    abstract：:The challenge of effectively delivering therapeutic agents to brain has led to an entire field of active research devoted to overcome the blood brain barrier (BBB) and efficiently deliver drugs to brain. This review focusses on exploring the facets of a novel platform designed for the delivery of drugs to brain. The p...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章,评审

    doi：10.3390/ijms17060806

    authors： Sharma G,Lakkadwala S,Modgil A,Singh J

    更新日期：2016-05-25 00:00:00

  • From General Aberrant Alternative Splicing in Cancers and Its Therapeutic Application to the Discovery of an Oncogenic DMTF1 Isoform.

    abstract：:Alternative pre-mRNA splicing is a crucial process that allows the generation of diversified RNA and protein products from a multi-exon gene. In tumor cells, this mechanism can facilitate cancer development and progression through both creating oncogenic isoforms and reducing the expression of normal or controllable p...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章,评审

    doi：10.3390/ijms18030191

    authors： Tian N,Li J,Shi J,Sui G

    更新日期：2017-03-02 00:00:00

  • Application of the Movable Type Free Energy Method to the Caspase-Inhibitor BindingAffinity Study.

    abstract：:Many studies have provided evidence suggesting that caspases not only contribute to the neurodegeneration associated with Alzheimer's disease (AD) but also play essential roles in promoting the underlying pathology of this disease. Studies regarding the caspase inhibition draw researchers' attention through time due t...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20194850

    authors： Xue S,Liu H,Zheng Z

    更新日期：2019-09-29 00:00:00

  • Genetic analysis of health-related secondary metabolites in a Brassica rapa recombinant inbred line population.

    abstract：:The genetic basis of the wide variation for nutritional traits in Brassica rapa is largely unknown. A new Recombinant Inbred Line (RIL) population was profiled using High Performance Liquid Chromatography (HPLC) and Nuclear Magnetic Resonance (NMR) analysis to detect quantitative trait loci (QTLs) controlling seed toc...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms140815561

    authors： Bagheri H,El-Soda M,Kim HK,Fritsche S,Jung C,Aarts MG

    更新日期：2013-07-25 00:00:00

  • Impact of Trail Running Races on Blood Viscosity and Its Determinants: Effects of Distance.

    abstract：:Blood rheology is a key determinant of tissue perfusion at rest and during exercise. The present study investigated the effects of race distance on hematological, blood rheological, and red blood cell (RBC) senescence parameters. Eleven runners participated in the Martigny-Combes à Chamonix 40 km race (MCC, elevation ...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms21228531

    authors： Robert M,Stauffer E,Nader E,Skinner S,Boisson C,Cibiel A,Feasson L,Renoux C,Robach P,Joly P,Millet GY,Connes P

    更新日期：2020-11-12 00:00:00

  • 1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione Induces G1 Cell Cycle Arrest and Autophagy in HeLa Cervical Cancer Cells.

    abstract：:The natural agent, 1-(2-hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione (HMDB), has been reported to have growth inhibitory effects on several human cancer cells. However, the role of HMDB in cervical cancer remains unclear. Herein, we found that HMDB dose- and time-dependently inhibited growth of HeLa cervical canc...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms17081274

    authors： Tsai JH,Hsu LS,Huang HC,Lin CL,Pan MH,Hong HM,Chen WJ

    更新日期：2016-08-05 00:00:00

  • Hydrothermal Synthesis Au-Bi2Te3 Nanocomposite Thermoelectric Film with a Hierarchical Sub-Micron Antireflection Quasi-Periodic Structure.

    abstract：:In this work, Au-Bi(2)Te(3) nanocomposite thermoelectric film with a hierarchical sub-micron antireflection quasi-periodic structure was synthesized via a low-temperature chemical route using Troides helena (Linnaeus) forewing (T_FW) as the biomimetic template. This method combines chemosynthesis with biomimetic techn...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms160612547

    authors： Tian J,Zhang W,Zhang Y,Xue R,Wang Y,Zhang Z,Zhang D

    更新日期：2015-06-03 00:00:00

  • Stress-Responsive Expression, Subcellular Localization and Protein-Protein Interactions of the Rice Metacaspase Family.

    abstract：:Metacaspases, a class of cysteine-dependent proteases like caspases in animals, are important regulators of programmed cell death (PCD) during development and stress responses in plants. The present study was focused on comprehensive analyses of expression patterns of the rice metacaspase (OsMC) genes in response to a...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms160716216

    authors： Huang L,Zhang H,Hong Y,Liu S,Li D,Song F

    更新日期：2015-07-17 00:00:00

  • Polyunsaturated Fatty Acids: What is Their Role in Treatment of Psychiatric Disorders?

    abstract：:In the central nervous system omega-3 fatty acids modulate cell signaling and affect dopaminergic and serotonergic pathways. On this basis, a new application for omega-3 fatty acids has been proposed, concerning the treatment of several psychiatric disorders. The present article is an update of a previous systematic r...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20215257

    authors： Bozzatello P,Rocca P,Mantelli E,Bellino S

    更新日期：2019-10-23 00:00:00

  • Decreased Expression of ZNF554 in Gliomas is Associated with the Activation of Tumor Pathways and Shorter Patient Survival.

    abstract：:Zinc finger protein 554 (ZNF554), a member of the Krüppel-associated box domain zinc finger protein subfamily, is predominantly expressed in the brain and placenta in humans. Recently, we unveiled that ZNF554 regulates trophoblast invasion during placentation and its decreased expression leads to the early pathogenesi...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms21165762

    authors： Balogh A,Reiniger L,Hetey S,Kiraly P,Toth E,Karaszi K,Juhasz K,Gelencser Z,Zvara A,Szilagyi A,Puskas LG,Matko J,Papp Z,Kovalszky I,Juhasz C,Than NG

    更新日期：2020-08-11 00:00:00

  • Nimodipine but Not Nifedipine Promotes Expression of Fatty Acid 2-Hydroxylase in a Surgical Stress Model Based on Neuro2a Cells.

    abstract：:Nimodipine is well characterized for the management of aneurysmal subarachnoid hemorrhage and has been shown to promote a better outcome and less delayed ischemic neurological deficits. Animal and clinical trials show neuroprotective efficacy following nerve injuries. We showed a neuroprotective effect on Neuro2a cell...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms18050964

    authors： Herzfeld E,Speh L,Strauss C,Scheller C

    更新日期：2017-05-03 00:00:00

  • Combined 3D-QSAR modeling and molecular docking studies on pyrrole-indolin-2-ones as Aurora A kinase inhibitors.

    abstract：:Aurora kinases have emerged as attractive targets for the design of anticancer drugs. 3D-QSAR (comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA)) and Surflex-docking studies were performed on a series of pyrrole-indoline-2-ones as Aurora A inhibitors. The CoMFA...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms12031605

    authors： Ai Y,Wang ST,Sun PH,Song FJ

    更新日期：2011-01-01 00:00:00

  • A Genomic Approach to Investigating Ocular Surface Microorganisms: Monitoring Core Microbiota on Eyelid Margin with a Dot hybridization Assay.

    abstract：:A sound ocular surface microbiota has been recognized as a part of ocular surface health following a growing body of evidence from next-generation sequencing technique and metagenomic analysis. However, even from the perspective of contemporary precision medicine, it is difficult to directly apply these new technologi...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms21218299

    authors： Kuo MT,Chao TL,Kuo SF,Chien CC,Chen A,Lai YH,Huang YT

    更新日期：2020-11-05 00:00:00

  • Correction: Elbadawy, M., et al. Novel Functions of Death-Associated Protein Kinases through Mitogen-Activated Protein Kinase-Related Signals. Int. J. Mol. Sci. 2018, 19, 3031.

    abstract：:The authors wish to make the following corrections to this paper [...]. ...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章,已发布勘误

    doi：10.3390/ijms21124560

    authors： Elbadawy M,Usui T,Yamawaki H,Sasaki K

    更新日期：2020-06-26 00:00:00

  • Stromal cell-derived factor 1 gene polymorphism is associated with susceptibility to adverse long-term allograft outcomes in non-diabetic kidney transplant recipients.

    abstract：:Although the genetic polymorphism of Stromal Cell-Derived Factor 1 (SDF-1) is associated with higher mortality of liver allograft recipients, the role of SDF-1 in the modulation of renal allograft outcomes is unclear. Between March 2000 and January 2008, we recruited 252 non-diabetic renal transplant recipients (RTRs)...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms150712495

    authors： Wang CJ,Tsai JP,Yang SF,Lian JD,Chang HR

    更新日期：2014-07-15 00:00:00

  • Citalopram Administration Does Not Promote Function or Histological Recovery after Spinal Cord Injury.

    abstract：:Citalopram is a selective serotonin reuptake inhibitor, and although widely used as an antidepressant, this drug has also demonstrated interesting repairing properties leading to motor recovery and pathology amelioration in animal models of stroke and degeneration. Here, we tested the efficacy of both 7-day and 8-week...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms21145062

    authors： Lima R,Monteiro S,Gomes ED,Vasconcelos NL,Assunção-Silva R,Morais M,Salgado AJ,Silva NA

    更新日期：2020-07-17 00:00:00

  • Mitochondrial AOX Supports Redox Balance of Photosynthetic Electron Transport, Primary Metabolite Balance, and Growth in Arabidopsis thaliana under High Light.

    abstract：:When leaves receive excess light energy, excess reductants accumulate in chloroplasts. It is suggested that some of the reductants are oxidized by the mitochondrial respiratory chain. Alternative oxidase (AOX), a non-energy conserving terminal oxidase, was upregulated in the photosynthetic mutant of Arabidopsis thalia...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20123067

    authors： Jiang Z,Watanabe CKA,Miyagi A,Kawai-Yamada M,Terashima I,Noguchi K

    更新日期：2019-06-23 00:00:00

  • Thermococcus Eurythermalis Endonuclease IV Can Cleave Various Apurinic/Apyrimidinic Site Analogues in ssDNA and dsDNA.

    abstract：:Endonuclease IV (EndoIV) is a DNA damage-specific endonuclease that mainly hydrolyzes the phosphodiester bond located at 5' of an apurinic/apyrimidinic (AP) site in DNA. EndoIV also possesses 3'-exonuclease activity for removing 3'-blocking groups and normal nucleotides. Here, we report that Thermococcus eurythermalis...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20010069

    authors： Wang WW,Zhou H,Xie JJ,Yi GS,He JH,Wang FP,Xiao X,Liu XP

    更新日期：2018-12-24 00:00:00

  • Heat Shock Proteins: Dynamic Biomolecules to Counter Plant Biotic and Abiotic Stresses.

    abstract：:Due to the present scenario of climate change, plants have to evolve strategies to survive and perform under a plethora of biotic and abiotic stresses, which restrict plant productivity. Maintenance of plant protein functional conformation and preventing non-native proteins from aggregation, which leads to metabolic d...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章,评审

    doi：10.3390/ijms20215321

    authors： Ul Haq S,Khan A,Ali M,Khattak AM,Gai WX,Zhang HX,Wei AM,Gong ZH

    更新日期：2019-10-25 00:00:00

  • Transcriptomic Signature of Right Ventricular Failure in Experimental Pulmonary Arterial Hypertension: Deep Sequencing Demonstrates Mitochondrial, Fibrotic, Inflammatory and Angiogenic Abnormalities.

    abstract：:Right ventricular failure (RVF) remains the leading cause of death in pulmonary arterial hypertension (PAH). We investigated the transcriptomic signature of RVF in hemodynamically well-phenotyped monocrotaline (MCT)-treated, male, Sprague-Dawley rats with severe PAH and decompensated RVF (increased right ventricular (...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms19092730

    authors： Potus F,Hindmarch CCT,Dunham-Snary KJ,Stafford J,Archer SL

    更新日期：2018-09-12 00:00:00

  • The influence of polyunsaturated fatty acids on the phospholipase D isoforms trafficking and activity in mast cells.

    abstract：:The impact of polyunsaturated fatty acid (PUFA) supplementation on phospholipase D (PLD) trafficking and activity in mast cells was investigated. The enrichment of mast cells with different PUFA including α-linolenic acid (LNA), eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), linoleic acid (LA) or arachidonic...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms14059005

    authors： Basiouni S,Fuhrmann H,Schumann J

    更新日期：2013-04-25 00:00:00

  • Epigenetic Mechanisms and Posttranslational Modifications in Systemic Lupus Erythematosus.

    abstract：:The complex physiology of eukaryotic cells is regulated through numerous mechanisms, including epigenetic changes and posttranslational modifications. The wide-ranging diversity of these mechanisms constitutes a way of dynamic regulation of the functionality of proteins, their activity, and their subcellular localizat...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章,评审

    doi：10.3390/ijms20225679

    authors： Navarro Quiroz E,Chavez-Estrada V,Macias-Ochoa K,Ayala-Navarro MF,Flores-Aguilar AS,Morales-Navarrete F,de la Cruz Lopez F,Gomez Escorcia L,Musso CG,Aroca Martinez G,Gonzales Torres H,Diaz Perez A,Cadena Bonfanti A,Sarmiento Gu

    更新日期：2019-11-13 00:00:00

  • Immune Complexes Impaired Glomerular Endothelial Cell Functions in Lupus Nephritis.

    abstract：:Lupus nephritis (LN) is one of the most common and severe complications of lupus. However, the mechanisms for renal damage have not been well elucidated. There are evidences show that glomerular endothelial cells (GECs) are damaged in LN. Immune complexes can deposit in subendothelial area and could affect GEC functio...

    journal_title：International journal of molecular sciences

    pub_type： 杂志文章

    doi：10.3390/ijms20215281

    authors： Wang L,Law HKW

    更新日期：2019-10-24 00:00:00

  • Calcium Signaling in Aging and Neurodegenerative Diseases 2019.

    abstract：:The European Calcium Society (ECS) workshop, which is held every 2 years, is a dedicated meeting of scientists interested in the elucidation of the action of calcium binding, calcium signaling and the study of proteins and organelles, such as mitochondria and endoplasmic reticulum, thereby involved, either in health a...

    journal_title：International journal of molecular sciences

    pub_type：

    doi：10.3390/ijms21031125

    authors： Cortes L,Malva J,Rego AC,Pereira CF

    更新日期：2020-02-07 00:00:00