Thermochemical esterifying citric acid onto lignocellulose for enhancing methylene blue sorption capacity of rice straw.

Abstract:

:In this paper, rice straw was esterified thermochemically with citric acid (CA) to produce potentially biodegradable cationic sorbent. The modified rice straw (MRS) and crude rice straw (CRS) were evaluated for their methylene blue (MB) removal capacity from aqueous solution. The effects of various experimental parameters (e.g., initial pH, sorbent dose, dye concentration, ion strength, and contact time) were examined. The ratio of MB sorbed on CRS increased as the initial pH was increased from pH 2 to 10. For MRS, the MB removal ratio came up to the maximum value beyond pH 3. The 1.5 g/l or up of MRS could almost completely remove the dye from 250 mg/l of MB solution. The ratio of MB sorbed kept above 98% over a range from 50 to 450 mg/l of MB concentration when 2.0 g/l of MRS was used. Increase in ion strength of solution induced decline of MB sorption. The isothermal data fitted the Langmuir model. The sorption processes followed the pseudo-first-order rate kinetics. The intraparticle diffusion rate constant (k(id)) was greatly increased due to modification.

journal_name

J Environ Manage

authors

Gong R,Zhong K,Hu Y,Chen J,Zhu G

doi

10.1016/j.jenvman.2007.04.004

subject

Has Abstract

pub_date

2008-09-01 00:00:00

pages

875-80

issue

4

eissn

0301-4797

issn

1095-8630

pii

S0301-4797(07)00165-X

journal_volume

88

pub_type

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