Structure of transition-metal cluster compounds: Use of an additional orbital resulting from the f, g character of spd bond orbitals.

Abstract:

:A general theory of the structure of complexes of the transition metals is developed on the basis of the enneacovalence of the metals and the requirements of the electroneutrality principle. An extra orbital may be provided through the small but not negligible amount of f and g character of spd bond orbitals, and an extra electron or electron pair may be accepted in this orbital for a single metal or a cluster to neutralize the positive electric charge resulting from the partial ionic character of the bonds with ligands, such as the carbonyl group. Examples of cluster compounds of cobalt, ruthenium, rhodium, osmium, and gold are discussed.

authors

Pauling L

doi

10.1073/pnas.74.12.5235

subject

Has Abstract

pub_date

1977-12-01 00:00:00

pages

5235-8

issue

12

eissn

0027-8424

issn

1091-6490

journal_volume

74

pub_type

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