Technique-sensitivity of contemporary adhesives.

Abstract:

:Besides micro-mechanical interlocking through hybrid-layer formation, self-etch adhesives may benefit from additional chemical interaction between the functional monomer and residual hydroxyapatite. One-step adhesives are commonly associated with lower bonding effectiveness, which must be attributed in part to the dissolution of hydrophilic and hydrophobic monomers in a relatively highly concentrated solvent. In this 'difficult' mixture, also water is essential as ionization medium to enable self-etching activity. Due to the high hydrophilicity, one-step self-etch adhesives have been reported to behave as semi-permeable membranes, allowing fluids to pass through and seriously jeopardizing bond durability. Recent research has also revealed that HEMA-free one-step adhesives are prone to phase-separation, which may also account for their lower bonding effectiveness. Employing an appropriate air-drying technique may, however, improve the bonding effectiveness of such phase-separating adhesives by getting rid of substantially more interfacial water than HEMA-containing adhesives, of which water might be more difficult to remove from.

journal_name

Dent Mater J

journal_title

Dental materials journal

authors

Van Meerbeek B,Van Landuyt K,De Munck J,Hashimoto M,Peumans M,Lambrechts P,Yoshida Y,Inoue S,Suzuki K

doi

10.4012/dmj.24.1

keywords:

subject

Has Abstract

pub_date

2005-03-01 00:00:00

pages

1-13

issue

1

eissn

0287-4547

issn

1881-1361

journal_volume

24

pub_type

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