Biomimetic apatite formation on polyethylene photografted with vinyltrimethoxysilane and hydrolyzed.

Abstract:

:A photografting technique to produce functional groups of silanol able to induce apatite nucleation was attempted on polyethylene substrate for biomimetic formation of bone-mineral-like apatite layer on its surface. The polyethylene surface was subjected to vapor-phase photografting of vinyltrimethoxysilane and subsequently to hydrolysis. The photografting formed methoxysilyl groups on the polyethylene substrate, which was changed into silanol groups successively by the hydrolysis in a hydrochloric solution. The polyethylene modified in this way formed a dense and homogeneous bone-mineral-like apatite layer in a solution with ion concentrations 1.5 times that of human blood plasma. This result indicates that the biomimetic process in combination with a polymeric grafting technique might provide a homogeneous bone-mineral-like apatite coating even on polymer fibers to be woven into an apatite-polymer composite with three-dimensional structure analogous to that of natural bone.

journal_name

Biomaterials

journal_title

Biomaterials

authors

Kim HM,Uenoyama M,Kokubo T,Minoda M,Miyamoto T,Nakamura T

doi

10.1016/s0142-9612(00)00437-3

keywords:

subject

Has Abstract

pub_date

2001-09-01 00:00:00

pages

2489-94

issue

18

eissn

0142-9612

issn

1878-5905

pii

S0142961200004373

journal_volume

22

pub_type

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